Polyyne synthesis evidenced by VUV spectroscopy of hydrocarbon-rich ices irradiated with energetic electrons

22 Oct 2019, 11:55
25m
Castello di Duino

Castello di Duino

Frazione Duino, 32, 34011 Duino-Aurisina, Trieste https://castellodiduino.it

Speaker

Prof. G. Strazzulla (INAF - Osservatorio Astrofisico di Catania, Italy)

Description

We present some results obtained by measuring VUV photoabsorption spectra in the range 110-340 nm of hydrocarbon-bearing ices and their mixtures with nitrogen. Samples have been irradiated with energetic (1 keV) electrons simulating conditions relevant to the icy bodies of the Solar System and icy mantles on grains in the interstellar or circumstellar medium. Ices in different astrophysical environments are continuosly exposed to energetic processing by photons, electrons and ions that contribute, sometimes dominate, to their physico-chemical evolution.
The results of this study indicate that many molecules among which polyynes H(−C≡C−)nH, are produced after irradition of pure CH4, C2H4 and C2H6 ices. Cyanopolyynes are synthesized when mixtures with nitrogen are irradiated. In addition, irradiation causes a spectral reddening (absorbance increases more at the shorter wavelengths than at the higher ones) and the formation of an unvolatile residuum whose spectral colors in the VUV range have been measured.
Results are discussed with a view to their astrophysical relevance with particular emphasis to the icy surfaces of Pluto and other Trans Neptunian Objects.

Primary authors

Dr S. Ioppolo (School of Electronic Engineering and Computer Science, Queen Mary University of London, UK ) Dr Z. Kanuchova (Astronomical Institute of Slovak Academy of Sciences, Tatranská Lomnica, Slovakia) Dr S.V. Hoffmann (Institute for Storage Ring Facilities, Dept. of Physics and Astronomy, Univ. Aarhus, Denmark) Dr N. Jones (Institute for Storage Ring Facilities, Dept. of Physics and Astronomy, Univ. Aarhus, Denmark) Prof. N.J. Mason (Department of Physical Sciences, The Open University, Milton Keynes, UK) Prof. G. Strazzulla (INAF - Osservatorio Astrofisico di Catania, Italy)

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